Length-dependent conductance of conjugated molecular wires synthesized by stepwise "click" chemistry

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Abstract

We report the preparation and electrical characterization of conjugated oligophenylenetriazole (OPT) wires having systematically varied lengths up to 10 nm. OPT wires were built from gold substrates using Cu(I)-catalyzed azide alkyne cycloaddition and characterized comprehensively by RAIRS, ellipsometry, and XPS. We observed a clear transition in direct current (DC) transport from tunneling to hopping in a length range between 4 and 5 nm as previously established for oligoarylimine wires. Stepwise click cycloaddition represents a new efficient method to prepare long conjugated molecular wire self-assembled monolayers (SAMs) on Au surfaces for conduction measurements and is expected to be compatible with a variety of functionalities and bonding architectures in the wire backbones.

Original languageEnglish (US)
Pages (from-to)8854-8855
Number of pages2
JournalJournal of the American Chemical Society
Volume132
Issue number26
DOIs
StatePublished - Jul 7 2010

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