TY - JOUR
T1 - Magnetocaloric effect and critical behavior in Pr0.5Sr 0.5MnO3
T2 - An analysis of the validity of the Maxwell relation and the nature of the phase transitions
AU - Caballero-Flores, R.
AU - Bingham, N. S.
AU - Phan, M. H.
AU - Torija, M. A.
AU - Leighton, C.
AU - Franco, V.
AU - Conde, A.
AU - Phan, T. L.
AU - Yu, S. C.
AU - Srikanth, H.
PY - 2014/6/16
Y1 - 2014/6/16
N2 - The Maxwell relation, the Clausius-Clapeyron equation, and a non-iterative method to obtain the critical exponents have been used to characterize the magnetocaloric effect (MCE) and the nature of the phase transitions in Pr 0.5Sr0.5MnO3, which undergoes a second-order paramagnetic to ferromagnetic (PM-FM) transition at , and a first-order ferromagnetic to antiferromagnetic (FM-AFM) transition at . We find that around the second-order PM-FM transition, the MCE (as represented by the magnetic entropy change, ΔSM) can be precisely determined from magnetization measurements using the Maxwell relation. However, around the first-order FM-AFM transition, values of ΔSM calculated with the Maxwell relation deviate significantly from those calculated by the Clausius-Clapeyron equation at the magnetic field and temperature ranges where a conversion between the AFM and FM phases occurs. A detailed analysis of the critical exponents of the second-order PM-FM transition allows us to correlate the short-range type magnetic interactions with the MCE. Using the Arrott-Noakes equation of state with the appropriate values of the critical exponents, the eld- and temperature-dependent magnetization curves, and hence the curves, have been simulated and compared with experimental data. A good agreement between the experimental and simulated data has been found in the vicinity of the Curie temperature TC, but a noticeable discrepancy is present for . This discrepancy arises mainly from the coexistence of AFM and FM phases and the presence of ferromagnetic clusters in the AFM matrix.
AB - The Maxwell relation, the Clausius-Clapeyron equation, and a non-iterative method to obtain the critical exponents have been used to characterize the magnetocaloric effect (MCE) and the nature of the phase transitions in Pr 0.5Sr0.5MnO3, which undergoes a second-order paramagnetic to ferromagnetic (PM-FM) transition at , and a first-order ferromagnetic to antiferromagnetic (FM-AFM) transition at . We find that around the second-order PM-FM transition, the MCE (as represented by the magnetic entropy change, ΔSM) can be precisely determined from magnetization measurements using the Maxwell relation. However, around the first-order FM-AFM transition, values of ΔSM calculated with the Maxwell relation deviate significantly from those calculated by the Clausius-Clapeyron equation at the magnetic field and temperature ranges where a conversion between the AFM and FM phases occurs. A detailed analysis of the critical exponents of the second-order PM-FM transition allows us to correlate the short-range type magnetic interactions with the MCE. Using the Arrott-Noakes equation of state with the appropriate values of the critical exponents, the eld- and temperature-dependent magnetization curves, and hence the curves, have been simulated and compared with experimental data. A good agreement between the experimental and simulated data has been found in the vicinity of the Curie temperature TC, but a noticeable discrepancy is present for . This discrepancy arises mainly from the coexistence of AFM and FM phases and the presence of ferromagnetic clusters in the AFM matrix.
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U2 - 10.1088/0953-8984/26/28/286001
DO - 10.1088/0953-8984/26/28/286001
M3 - Article
C2 - 24945593
AN - SCOPUS:84902990120
SN - 0953-8984
VL - 26
JO - Journal of Physics Condensed Matter
JF - Journal of Physics Condensed Matter
IS - 28
M1 - 286001
ER -