Manganese fischer carbene chemistry: Reactions of cpʹ(co)2mn=c(ome/oli)r with enynes, 1-hexyne, and acrylates

Thomas R. Hoye; Gretchen M. Rehberg

doi:10.1021/om00162a005

Manganese fischer carbene chemistry: Reactions of cpʹ(co)₂mn=c(ome/oli)r with enynes, 1-hexyne, and acrylates

Thomas R. Hoye, Gretchen M. Rehberg

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Reactions of the title carbene complexes, both the neutral methoxy (1a,b) and anionic “lithoxy” (1c) versions, with α,ω-enynes 2 give the bicyclic cyclopropanes 3. The anion also reacts with 1-hexyne to give the butenolide 5 and with acrylate esters to give the γ-keto esters 8.

Original language	English (US)
Pages (from-to)	3014-3015
Number of pages	2
Journal	Organometallics
Volume	9
Issue number	12
DOIs	https://doi.org/10.1021/om00162a005
State	Published - Jan 1 1990

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Manganese fischer carbene chemistry: Reactions of cpʹ(co)₂mn=c(ome/oli)r with enynes, 1-hexyne, and acrylates

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