Mechanism of Nitrogenase H₂ Formation by Metal-Hydride Protonation Probed by Mediated Electrocatalysis and H/D Isotope Effects

Engineering & Materials Science

• Protonation 99%
• Electrocatalysis 99%
• Hydrides 68%
• Isotopes 66%
• Protons 39%
• Metals 34%
• Electrons 32%
• Proteins 29%
• Oxidoreductases 16%
• Density functional theory 16%
• Substrates 15%
• Peptides 14%
• Adenosinetriphosphate 14%
• Biomimetics 13%
• Enzymes 12%
• Ammonia 11%

Medicine & Life Sciences

• Molybdoferredoxin 100%
• Nitrogenase 86%
• Isotopes 59%
• Metals 47%
• Protons 33%
• Electrons 26%
• Catalytic Domain 19%
• Density Functional Theory 19%
• Biomimetics 13%
• Equipment and Supplies 13%
• Ammonia 12%
• Oxidoreductases 10%
• Adenosine Triphosphate 8%
• Kinetics 7%
• Amino Acids 7%
• Peptides 6%
• Enzymes 5%
• Proteins 4%

Chemical Compounds

• Metal Hydride 65%
• Electrocatalysis 58%
• Isotope Effect 55%
• Hydride 46%
• Proton 35%
• Electron Particle 29%
• Protein 22%
• Dinitrogen 21%
• Reductive Elimination Reaction 19%
• Reduction 16%
• Transition State 14%
• Ammonia 13%
• Density Functional Theory 11%
• Peptide 10%
• Environment 10%
• Acid 6%