Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen. LXX. Erste Arylrheniumoxide (σ-Aryl)ReO3

Wolfgang A. Herrmann, Monika Ladwig, Paul Kiprof, Jürgen Riede

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Abstract

The first examples of arylmetal oxides of general formula (σ-aryl)MOx have been synthesized, for M = Re. The compounds (σ-aryl)ReO3 (3) are obtained in a simple, ostensibly general route by treatment of dirhenium heptoxide with the corresponding arylzinc compound Zn(σ-aryl)2. As side product, the zinc perrhenate Zn(thf)2(ReO4)2 formed and precipitated as insoluble material from the solution. (Mesityltrioxo)rhenium(VII) was characterized by an X-ray diffraction study (pyramidal geometry).

Original languageGerman
Pages (from-to)C13-C17
JournalJournal of Organometallic Chemistry
Volume371
Issue number1
DOIs
StatePublished - Jul 18 1989

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