Mercury Capture from Petroleum Using Deep Eutectic Solvents

Samah E.E. Warrag, Evgenii O. Fetisov, Dannie J.G.P. Van Osch, David B. Harwood, Maaike C. Kroon, J. Ilja Siepmann, Cor J. Peters

Research output: Contribution to journalArticlepeer-review

9 Scopus citations


Mercury capture is a major challenge in petroleum and natural gas processing. Recently, ionic liquids (ILs) have been introduced as mercury extractants from oil and gas. ILs yield very high mercury extraction efficiencies (>95%) from hydrocarbons, but their drawbacks include complex synthesis, toxicity, and difficult regeneration after mercury capture. In this work, a new technology using deep eutectic solvents (DESs) for elemental mercury (Hg0) extraction from hydrocarbons is demonstrated. DESs are an innovative class of designer solvents exhibiting similar properties as ILs, such as low vapor pressure and low flammability, but DESs are formed from inexpensive hydrogen-bond donor and acceptor compounds that are often biodegradable. In this work, four DESs were investigated including choline chloride:urea, choline chloride:ethylene glycol, choline chloride:levulinic acid, and betaine:levulinic acid, where the molar ratio is 1:2 in all cases. The DESs were tested for their thermal stability, density, and viscosity. Their performance for mercury extraction was assessed using saturated solutions in n-dodecane as the model oil. It was found that solvent to feed ratios of 1:1 and 2:1 at temperatures of 303.15 and 333.15 K and atmospheric pressure yield extraction efficiencies greater than 80% for all four DESs. First-principles molecular dynamics simulations probing the solvation in choline chloride:urea indicate a tight first coordination shell for mercury. Calculation of the Hg-Hg potential of mean force supports formation of a mercury-mercury polycation for a pair of Hg1+ ions, but not for pairs of Hg0 and Hg2+ species. Geometric analysis of the speciation and Mulliken population analysis support a redox reaction involving Hg2+ + 2Cl-.

Original languageEnglish (US)
Pages (from-to)9222-9230
Number of pages9
JournalIndustrial and Engineering Chemistry Research
Issue number28
StatePublished - Jul 18 2018

Bibliographical note

Funding Information:
Financial support for this collaborative project at the Petroleum Institute (PI) and at the University of Minnesota from the Petroleum Institute Research Center (PIRC) through a grant entitled “Advanced PVT-Properties and Molecular Modeling of Complex Fluids in Support of Safe and Green Hydrocarbon Production” (Project Code LTR14009) is gratefully acknowledged. The authors also thank Eindhoven University of Technology (TU/e) for the kind hospitality in the Separation Technology Group (SEP). Sincere gratitude goes to SEP team members and W. Weggemans for their help in the experimental activates. Computer resources were provided by the Minnesota Supercomputing Institute.

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