Micellization of PS-PMMA diblock copolymers in an ionic liquid

Peter M. Simone, Timothy P. Lodge

Research output: Contribution to journalArticlepeer-review

53 Scopus citations


Three polystyrene-block-poly(methyl methacrylate) (PS-PMMA) block copolymers with varying molecular content have been shown to form micelles when dissolved in the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM PF6). The micellar structure was studied via cryogenic transmission electron microscopy and dynamic light scattering, and a morphological transition from spherical to cylindrical micelles was observed upon reduction of the PMMA volume fraction. The possibility of frozen micellar morphology was considered, due to the solution preparation method and high glass transition temperature (Tg) of the PS blocks that form the micellar cores. By comparison of the behavior of a 100 kDa PMMA homopolymer dissolved in both BMIM PF6 and a known good solvent, acetone, it was determined that BMIM PF6 behaves as a good solvent for PMMA. It was also observed that extended exposure to the electron beam during cryogenic transmission electron microscopy could damage the copolymer micelles and result in a reversal of contrast.

Original languageEnglish (US)
Pages (from-to)339-348
Number of pages10
JournalMacromolecular Chemistry and Physics
Issue number4
StatePublished - Feb 21 2007


  • Block copolymers
  • Cryogenic transmission electron microscopy
  • Dynamic light scattering
  • Ionic liquids
  • Micelles


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