Abstract
Mild and efficient method for the preparation of iodylarenes by oxidation of iodoarenes with Oxone in aqueous acetonitrile at room temperature is described. This new procedure allows the preparation of various iodylarenes with electron-donating or electron-withdrawing substituents in the aromatic ring including the previously unknown 1,2-diiodylbenzene.
Original language | English (US) |
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Pages (from-to) | 4254-4256 |
Number of pages | 3 |
Journal | Tetrahedron Letters |
Volume | 57 |
Issue number | 37 |
DOIs | |
State | Published - 2016 |
Bibliographical note
Funding Information:This work was supported by research grants from the National Science Foundation ( CHE-1262479 and MRI-1420373 ) and by the Russian Science Foundation ( RSF-16-13-10081 ).
Publisher Copyright:
© 2016 Elsevier Ltd
Keywords
- Hypervalent iodine
- Iodine
- Iodylarenes
- Oxidation
- Oxone