Mild and efficient synthesis of iodylarenes using Oxone as oxidant

Natalia Soldatova, Pavel Postnikov, Anna A. Troyan, Akira Yoshimura, Mekhman S. Yusubov, Viktor Zhdankin

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

Mild and efficient method for the preparation of iodylarenes by oxidation of iodoarenes with Oxone in aqueous acetonitrile at room temperature is described. This new procedure allows the preparation of various iodylarenes with electron-donating or electron-withdrawing substituents in the aromatic ring including the previously unknown 1,2-diiodylbenzene.

Original languageEnglish (US)
Pages (from-to)4254-4256
Number of pages3
JournalTetrahedron Letters
Volume57
Issue number37
DOIs
StatePublished - 2016

Bibliographical note

Funding Information:
This work was supported by research grants from the National Science Foundation ( CHE-1262479 and MRI-1420373 ) and by the Russian Science Foundation ( RSF-16-13-10081 ).

Publisher Copyright:
© 2016 Elsevier Ltd

Keywords

  • Hypervalent iodine
  • Iodine
  • Iodylarenes
  • Oxidation
  • Oxone

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