TY - JOUR
T1 - New classes of zerovalent titanium carbonyls; first structural characterisation of a seven-co-ordinate titanium complex containing only unidentate ligands
T2 - Ti(CO)5(SnPh3)2 2- 1
AU - Chi, Kai Ming
AU - Frerichs, Scott R.
AU - Ellis, John E.
PY - 1988/1/1
Y1 - 1988/1/1
N2 - Seven-co-ordinate zerovalent titanium carbonyls containing only unidentate ligands, Ti(CO)5(EPh3)22- (E = Ge, Sn, structurally characterized for Sn), and organoarsine and arylphosphine ligands, Ti(CO)3[o-C6H4(AsMe2) 2]2 and Ti(CO)4[MeC(CH2PPh 2)3], respectively, have been prepared for the first time from highly reactive and quite thermally unstable low valent titanium intermediates, one of which has been characterized as Ti(CO) 5(PMe3)2 on the basis of 13C and 31P n.m.r. spectra.
AB - Seven-co-ordinate zerovalent titanium carbonyls containing only unidentate ligands, Ti(CO)5(EPh3)22- (E = Ge, Sn, structurally characterized for Sn), and organoarsine and arylphosphine ligands, Ti(CO)3[o-C6H4(AsMe2) 2]2 and Ti(CO)4[MeC(CH2PPh 2)3], respectively, have been prepared for the first time from highly reactive and quite thermally unstable low valent titanium intermediates, one of which has been characterized as Ti(CO) 5(PMe3)2 on the basis of 13C and 31P n.m.r. spectra.
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U2 - 10.1039/C39880001013
DO - 10.1039/C39880001013
M3 - Article
AN - SCOPUS:37049081015
SN - 0022-4936
SP - 1013
EP - 1015
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 15
ER -