New disordering mode for TFSI- anions: The nonequilibrium, plastic crystalline structure of Et4NTFSI

Wesley A. Henderson, Marie Herstedt, Victor G. Young, Stefano Passerini, Hugh C. De Long, Paul C. Trulove

Research output: Contribution to journalArticlepeer-review

70 Scopus citations

Abstract

A new TFSI- anion disordering mode has been discovered in a supercooled plastic crystalline phase of Et4NTFSI, which may, in part, account for the low melting points of TFSI- salts with organic cations, thereby forming ionic liquids, and the intriguing properties of LiTFSI for lithium battery applications.

Original languageEnglish (US)
Pages (from-to)1412-1414
Number of pages3
JournalInorganic chemistry
Volume45
Issue number4
DOIs
StatePublished - Feb 20 2006

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