NEW VINYL ORGANOMETALLIC MONOMERS: SYNTHESIS AND POLYMERIZATION BEHAVIOR.

Marvin D. Rausch, David W. Macomber, Francis G. Fang, Charles U. Pittman, T. V. Jayaraman, Ralph D. Priester

Research output: Chapter in Book/Report/Conference proceedingConference contribution

3 Scopus citations

Abstract

In this work, ( eta **5-vinylcyclopentadienyl)tricarbonyl-manganese, ( eta **5-vinylcyclopentadienyl)dicarbonylnitrosylchromium,and 3-vinylbisfulvalenediiron were prepared. In each case, the synthetic route involved Friedel-Crafts acylation of the Cp-metal complex followed by hydride reduction of the acetyl carbonyl function to an alcohol, and dehydration. Polymerization studies of these monomers under free-radical of cationic initiation conditions are being studied and some results are discussed.

Original languageEnglish (US)
Title of host publicationPolymer Science and Technology
EditorsBill M. Culbertson, Charles U.Jr. Pittman
PublisherPlenum Press
Pages243-267
Number of pages25
ISBN (Print)0306414775
StatePublished - 1984

Publication series

NamePolymer Science and Technology
Volume25
ISSN (Print)0093-6286

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