Novel Functionalized Trisubstituted Allylboronates via Hosomi-Miyaura Borylation of Functionalized Allyl Acetates

P. Veeraraghavan Ramachandran; Debarshi Pratihar; Debanjan Biswas; Amit Srivastava; M. Venkat Ram Reddy

doi:10.1021/ol035952z

Novel Functionalized Trisubstituted Allylboronates via Hosomi-Miyaura Borylation of Functionalized Allyl Acetates

P. Veeraraghavan Ramachandran, Debarshi Pratihar, Debanjan Biswas, Amit Srivastava, M. Venkat Ram Reddy

Chemistry & Biochemistry

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Abstract

(Equation presented) A series of novel functionalized achiral and chiral allylboronates have been synthesized via the nucleophilic addition of boronates on allyl acetates derived via vinylalumination or Baylis-Hillman reaction of aldehydes. These reagents, upon allylboration with aldehydes, furnish β-substituted-α-methylene-γ-butyrolactones stereoselectively.

Original language	English (US)
Pages (from-to)	481-484
Number of pages	4
Journal	Organic Letters
Volume	6
Issue number	4
DOIs	https://doi.org/10.1021/ol035952z
State	Published - Feb 19 2004

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title = "Novel Functionalized Trisubstituted Allylboronates via Hosomi-Miyaura Borylation of Functionalized Allyl Acetates",

abstract = "(Equation presented) A series of novel functionalized achiral and chiral allylboronates have been synthesized via the nucleophilic addition of boronates on allyl acetates derived via vinylalumination or Baylis-Hillman reaction of aldehydes. These reagents, upon allylboration with aldehydes, furnish β-substituted-α-methylene-γ-butyrolactones stereoselectively.",

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doi = "10.1021/ol035952z",

language = "English (US)",

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journal = "Organic Letters",

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T1 - Novel Functionalized Trisubstituted Allylboronates via Hosomi-Miyaura Borylation of Functionalized Allyl Acetates

AU - Ramachandran, P. Veeraraghavan

AU - Pratihar, Debarshi

AU - Biswas, Debanjan

AU - Srivastava, Amit

AU - Reddy, M. Venkat Ram

PY - 2004/2/19

Y1 - 2004/2/19

N2 - (Equation presented) A series of novel functionalized achiral and chiral allylboronates have been synthesized via the nucleophilic addition of boronates on allyl acetates derived via vinylalumination or Baylis-Hillman reaction of aldehydes. These reagents, upon allylboration with aldehydes, furnish β-substituted-α-methylene-γ-butyrolactones stereoselectively.

AB - (Equation presented) A series of novel functionalized achiral and chiral allylboronates have been synthesized via the nucleophilic addition of boronates on allyl acetates derived via vinylalumination or Baylis-Hillman reaction of aldehydes. These reagents, upon allylboration with aldehydes, furnish β-substituted-α-methylene-γ-butyrolactones stereoselectively.

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JO - Organic Letters

JF - Organic Letters

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ER -

Novel Functionalized Trisubstituted Allylboronates via Hosomi-Miyaura Borylation of Functionalized Allyl Acetates

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