Novel Functionalized Trisubstituted Allylboronates via Hosomi-Miyaura Borylation of Functionalized Allyl Acetates

P. Veeraraghavan Ramachandran, Debarshi Pratihar, Debanjan Biswas, Amit Srivastava, M. Venkat Ram Reddy

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Abstract

(Equation presented) A series of novel functionalized achiral and chiral allylboronates have been synthesized via the nucleophilic addition of boronates on allyl acetates derived via vinylalumination or Baylis-Hillman reaction of aldehydes. These reagents, upon allylboration with aldehydes, furnish β-substituted-α-methylene-γ-butyrolactones stereoselectively.

Original languageEnglish (US)
Pages (from-to)481-484
Number of pages4
JournalOrganic Letters
Volume6
Issue number4
DOIs
StatePublished - Feb 19 2004

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