Novel gold derivatives of titanium carbonyl and structural characterization of a compound containing an unsupported gold-titanium bond: [Ti(CO)6(AuPEt3)]-

Paul J. Fischer; Victor G. Young; John E. Ellis

doi:10.1039/a701143a

Novel gold derivatives of titanium carbonyl and structural characterization of a compound containing an unsupported gold-titanium bond: [Ti(CO)₆(AuPEt₃)]^-

Paul J. Fischer, Victor G. Young, John E. Ellis

Chemistry (Twin Cities)

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Abstract

Hexacarbonyltitanate(2-) reacts with (R₃P)AuCl (R = C₆H₁₁, Et) to provide the first anions of the general formula [M(CO)_x(AuPR₃)_y]^z, and a structurally characterized (for R = Et) compound containing a largely unsupported gold-titanium bond.

Original language	English (US)
Pages (from-to)	1249-1250
Number of pages	2
Journal	Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/a701143a
State	Published - 1997

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title = "Novel gold derivatives of titanium carbonyl and structural characterization of a compound containing an unsupported gold-titanium bond: [Ti(CO)6(AuPEt3)]-",

abstract = "Hexacarbonyltitanate(2-) reacts with (R3P)AuCl (R = C6H11, Et) to provide the first anions of the general formula [M(CO)x(AuPR3)y]z, and a structurally characterized (for R = Et) compound containing a largely unsupported gold-titanium bond.",

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AU - Ellis, John E.

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Novel gold derivatives of titanium carbonyl and structural characterization of a compound containing an unsupported gold-titanium bond: [Ti(CO)₆(AuPEt₃)]^-

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