Novel gold derivatives of titanium carbonyl and structural characterization of a compound containing an unsupported gold-titanium bond: [Ti(CO)6(AuPEt3)]-

Paul J. Fischer, Victor G. Young, John E. Ellis

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Abstract

Hexacarbonyltitanate(2-) reacts with (R3P)AuCl (R = C6H11, Et) to provide the first anions of the general formula [M(CO)x(AuPR3)y]z, and a structurally characterized (for R = Et) compound containing a largely unsupported gold-titanium bond.

Original languageEnglish (US)
Pages (from-to)1249-1250
Number of pages2
JournalChemical Communications
Issue number13
DOIs
StatePublished - Jan 1 1997

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