One-dimensional Cu(II) coordination polymers: Tuning the structure by modulating the "carboxylate arm" lengths of polycarboxylate ligands

Ramadan Abuhmaiera; Yanhua Lan; Ayuk M. Ako; George E. Kostakis; Andreas Mavrantonakis; Wim Klopper; Rodolphe Clérac; Christopher E. Anson; Annie K. Powell

doi:10.1039/b820834d

One-dimensional Cu(II) coordination polymers: Tuning the structure by modulating the "carboxylate arm" lengths of polycarboxylate ligands

Ramadan Abuhmaiera, Yanhua Lan, Ayuk M. Ako, George E. Kostakis, Andreas Mavrantonakis, Wim Klopper, Rodolphe Clérac, Christopher E. Anson, Annie K. Powell

Chemistry (Twin Cities)

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Abstract

To understand the influence of the ligand on crystal growth, two new polycarboxylate ligands, 2-(carboxyphenyl)iminoacetic propanoic acid (H ₃cpiap) and 2-(carboxyphenyl)iminodipropanoic acid (H ₃cpidp), have been synthesized. The reaction of each with Cu(NO ₃)₂·3H₂O under similar reaction conditions yields two 1D coordination polymers {[Cu₃(cpiap) ₂(H₂O)₃](-H₂O)}_n· 7nH₂O (1) and [Cu(H₂cpidp)₂(H ₂O)₂]_n·4nH₂O (2), respectively. A T5(2) 1D water tape constructed from an edge-sharing cyclic pentamer has been observed in compound 1, in which the water chains interact with the 1D coordination polymer chains to form a 3D supramolecular binodal (5,8)-network through hydrogen-bonding interactions.

Original language	English (US)
Pages (from-to)	1089-1096
Number of pages	8
Journal	CrystEngComm
Volume	11
Issue number	6
DOIs	https://doi.org/10.1039/b820834d
State	Published - 2009

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title = "One-dimensional Cu(II) coordination polymers: Tuning the structure by modulating the {"}carboxylate arm{"} lengths of polycarboxylate ligands",

abstract = "To understand the influence of the ligand on crystal growth, two new polycarboxylate ligands, 2-(carboxyphenyl)iminoacetic propanoic acid (H 3cpiap) and 2-(carboxyphenyl)iminodipropanoic acid (H 3cpidp), have been synthesized. The reaction of each with Cu(NO 3)2·3H2O under similar reaction conditions yields two 1D coordination polymers {[Cu3(cpiap) 2(H2O)3](-H2O)}n· 7nH2O (1) and [Cu(H2cpidp)2(H 2O)2]n·4nH2O (2), respectively. A T5(2) 1D water tape constructed from an edge-sharing cyclic pentamer has been observed in compound 1, in which the water chains interact with the 1D coordination polymer chains to form a 3D supramolecular binodal (5,8)-network through hydrogen-bonding interactions.",

author = "Ramadan Abuhmaiera and Yanhua Lan and Ako, {Ayuk M.} and Kostakis, {George E.} and Andreas Mavrantonakis and Wim Klopper and Rodolphe Cl{\'e}rac and Anson, {Christopher E.} and Powell, {Annie K.}",

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doi = "10.1039/b820834d",

language = "English (US)",

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T1 - One-dimensional Cu(II) coordination polymers

T2 - Tuning the structure by modulating the "carboxylate arm" lengths of polycarboxylate ligands

AU - Abuhmaiera, Ramadan

AU - Lan, Yanhua

AU - Ako, Ayuk M.

AU - Kostakis, George E.

AU - Mavrantonakis, Andreas

AU - Klopper, Wim

AU - Clérac, Rodolphe

AU - Anson, Christopher E.

AU - Powell, Annie K.

PY - 2009

Y1 - 2009

N2 - To understand the influence of the ligand on crystal growth, two new polycarboxylate ligands, 2-(carboxyphenyl)iminoacetic propanoic acid (H 3cpiap) and 2-(carboxyphenyl)iminodipropanoic acid (H 3cpidp), have been synthesized. The reaction of each with Cu(NO 3)2·3H2O under similar reaction conditions yields two 1D coordination polymers {[Cu3(cpiap) 2(H2O)3](-H2O)}n· 7nH2O (1) and [Cu(H2cpidp)2(H 2O)2]n·4nH2O (2), respectively. A T5(2) 1D water tape constructed from an edge-sharing cyclic pentamer has been observed in compound 1, in which the water chains interact with the 1D coordination polymer chains to form a 3D supramolecular binodal (5,8)-network through hydrogen-bonding interactions.

AB - To understand the influence of the ligand on crystal growth, two new polycarboxylate ligands, 2-(carboxyphenyl)iminoacetic propanoic acid (H 3cpiap) and 2-(carboxyphenyl)iminodipropanoic acid (H 3cpidp), have been synthesized. The reaction of each with Cu(NO 3)2·3H2O under similar reaction conditions yields two 1D coordination polymers {[Cu3(cpiap) 2(H2O)3](-H2O)}n· 7nH2O (1) and [Cu(H2cpidp)2(H 2O)2]n·4nH2O (2), respectively. A T5(2) 1D water tape constructed from an edge-sharing cyclic pentamer has been observed in compound 1, in which the water chains interact with the 1D coordination polymer chains to form a 3D supramolecular binodal (5,8)-network through hydrogen-bonding interactions.

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DO - 10.1039/b820834d

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JF - CrystEngComm

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ER -

One-dimensional Cu(II) coordination polymers: Tuning the structure by modulating the "carboxylate arm" lengths of polycarboxylate ligands

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