ortho-Hydroxylation of benzoic acids with hydrogen peroxide at a non-heme iron center

Sonia Taktak; Margaret Flook; Bruce M. Foxman; Lawrence Que; Elena V. Rybak-Akimova

doi:10.1039/b508004e

ortho-Hydroxylation of benzoic acids with hydrogen peroxide at a non-heme iron center

Sonia Taktak, Margaret Flook, Bruce M. Foxman, Lawrence Que, Elena V. Rybak-Akimova

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

85 Scopus citations

Abstract

The iron-assisted hydroxylation of benzoic acid to salicylic acid by 1/H₂O₂ has been achieved in good yield under mild conditions (where 1 is [Fe(II)(BPMEN)(CH₃CN)₂](CIO ₄)₂ and BPMEN = N,Ń-dimethyl-N,Ń-bis(2- pyridylmethyl)ethane-1,2-diamine); the product of this reaction is a novel mononuclear iron(m) complex with a chelating salicylate.

Original language	English (US)
Pages (from-to)	5301-5303
Number of pages	3
Journal	Chemical Communications
Issue number	42
DOIs	https://doi.org/10.1039/b508004e
State	Published - Nov 14 2005

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title = "ortho-Hydroxylation of benzoic acids with hydrogen peroxide at a non-heme iron center",

abstract = "The iron-assisted hydroxylation of benzoic acid to salicylic acid by 1/H2O2 has been achieved in good yield under mild conditions (where 1 is [Fe(II)(BPMEN)(CH3CN)2](CIO 4)2 and BPMEN = N,{\'N}-dimethyl-N,{\'N}-bis(2- pyridylmethyl)ethane-1,2-diamine); the product of this reaction is a novel mononuclear iron(m) complex with a chelating salicylate.",

author = "Sonia Taktak and Margaret Flook and Foxman, {Bruce M.} and Lawrence Que and Rybak-Akimova, {Elena V.}",

year = "2005",

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doi = "10.1039/b508004e",

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pages = "5301--5303",

journal = "Chemical Communications",

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T1 - ortho-Hydroxylation of benzoic acids with hydrogen peroxide at a non-heme iron center

AU - Taktak, Sonia

AU - Flook, Margaret

AU - Foxman, Bruce M.

AU - Que, Lawrence

AU - Rybak-Akimova, Elena V.

PY - 2005/11/14

Y1 - 2005/11/14

N2 - The iron-assisted hydroxylation of benzoic acid to salicylic acid by 1/H2O2 has been achieved in good yield under mild conditions (where 1 is [Fe(II)(BPMEN)(CH3CN)2](CIO 4)2 and BPMEN = N,Ń-dimethyl-N,Ń-bis(2- pyridylmethyl)ethane-1,2-diamine); the product of this reaction is a novel mononuclear iron(m) complex with a chelating salicylate.

AB - The iron-assisted hydroxylation of benzoic acid to salicylic acid by 1/H2O2 has been achieved in good yield under mild conditions (where 1 is [Fe(II)(BPMEN)(CH3CN)2](CIO 4)2 and BPMEN = N,Ń-dimethyl-N,Ń-bis(2- pyridylmethyl)ethane-1,2-diamine); the product of this reaction is a novel mononuclear iron(m) complex with a chelating salicylate.

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SP - 5301

EP - 5303

JO - Chemical Communications

JF - Chemical Communications

IS - 42

ER -

ortho-Hydroxylation of benzoic acids with hydrogen peroxide at a non-heme iron center

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