O2 chemistry of dicopper complexes with alkyltriamine ligands. Comparing synergistic effects on O2 binding

Anna Company; Diana Lamata; Albert Poater; Miquel Solà; Elena V. Rybak-Akimova; Lawrence Que; Xavier Fontrodona; Teodor Parella; Antoni Llobet; Miquel Costas

doi:10.1021/ic0602446

O₂ chemistry of dicopper complexes with alkyltriamine ligands. Comparing synergistic effects on O₂ binding

Anna Company, Diana Lamata, Albert Poater, Miquel Solà, Elena V. Rybak-Akimova, Lawrence Que, Xavier Fontrodona, Teodor Parella, Antoni Llobet, Miquel Costas

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Two dicopper(I) complexes containing tertiary N-methylated hexaaza ligands which impose different steric constraints to the Cu ions have been synthesized, and their reactivity toward O₂ has been compared with a mononuclear related system, highlighting the importance of cooperative effects between the metal centers in O₂ activation.

Original language	English (US)
Pages (from-to)	5239-5241
Number of pages	3
Journal	Inorganic chemistry
Volume	45
Issue number	14
DOIs	https://doi.org/10.1021/ic0602446
State	Published - Jul 10 2006

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O₂ chemistry of dicopper complexes with alkyltriamine ligands. Comparing synergistic effects on O₂ binding. / Company, Anna; Lamata, Diana; Poater, Albert; Solà, Miquel; Rybak-Akimova, Elena V.; Que, Lawrence; Fontrodona, Xavier; Parella, Teodor; Llobet, Antoni; Costas, Miquel.

In: Inorganic chemistry, Vol. 45, No. 14, 10.07.2006, p. 5239-5241.

Research output: Contribution to journal › Article › peer-review

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AU - Que, Lawrence

AU - Fontrodona, Xavier

AU - Parella, Teodor

AU - Llobet, Antoni

AU - Costas, Miquel

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AB - Two dicopper(I) complexes containing tertiary N-methylated hexaaza ligands which impose different steric constraints to the Cu ions have been synthesized, and their reactivity toward O2 has been compared with a mononuclear related system, highlighting the importance of cooperative effects between the metal centers in O2 activation.

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