Phase behavior of microemulsions made with n-alkyl monoglucosides and n-alkyl polyglycol ethers

Larry D. Ryan; Kai V. Schubert; Eric W. Kaler

doi:10.1021/la9608730

Phase behavior of microemulsions made with n-alkyl monoglucosides and n-alkyl polyglycol ethers

Larry D. Ryan, Kai V. Schubert, Eric W. Kaler

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Abstract

The phase behavior of mixtures of water, octane, n-alkyl polyglycol ethers (C_iE_j), and n-alkyl β-D-glucopyranosides (C_mG₁) is systematically studied as a function of temperature and composition. The addition of C_mG₁ to water-octane-C_iE_j mixtures promoted formation of a three-phase region that is nearly independent of temperature in all mixtures studied. The size and extent of this three-phase region are shown as a function of C_mG₁ concentration and hydrophibicity and C_iE_j amphiphilicity. This unique behavior arises from the extremely low oil solubility of the alkyl monoglucosides.

Original language	English (US)
Pages (from-to)	1510-1518
Number of pages	9
Journal	Langmuir
Volume	13
Issue number	6
DOIs	https://doi.org/10.1021/la9608730
State	Published - Mar 19 1997

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title = "Phase behavior of microemulsions made with n-alkyl monoglucosides and n-alkyl polyglycol ethers",

abstract = "The phase behavior of mixtures of water, octane, n-alkyl polyglycol ethers (CiEj), and n-alkyl β-D-glucopyranosides (CmG1) is systematically studied as a function of temperature and composition. The addition of CmG1 to water-octane-CiEj mixtures promoted formation of a three-phase region that is nearly independent of temperature in all mixtures studied. The size and extent of this three-phase region are shown as a function of CmG1 concentration and hydrophibicity and CiEj amphiphilicity. This unique behavior arises from the extremely low oil solubility of the alkyl monoglucosides.",

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AU - Kaler, Eric W.

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N2 - The phase behavior of mixtures of water, octane, n-alkyl polyglycol ethers (CiEj), and n-alkyl β-D-glucopyranosides (CmG1) is systematically studied as a function of temperature and composition. The addition of CmG1 to water-octane-CiEj mixtures promoted formation of a three-phase region that is nearly independent of temperature in all mixtures studied. The size and extent of this three-phase region are shown as a function of CmG1 concentration and hydrophibicity and CiEj amphiphilicity. This unique behavior arises from the extremely low oil solubility of the alkyl monoglucosides.

AB - The phase behavior of mixtures of water, octane, n-alkyl polyglycol ethers (CiEj), and n-alkyl β-D-glucopyranosides (CmG1) is systematically studied as a function of temperature and composition. The addition of CmG1 to water-octane-CiEj mixtures promoted formation of a three-phase region that is nearly independent of temperature in all mixtures studied. The size and extent of this three-phase region are shown as a function of CmG1 concentration and hydrophibicity and CiEj amphiphilicity. This unique behavior arises from the extremely low oil solubility of the alkyl monoglucosides.

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Phase behavior of microemulsions made with n-alkyl monoglucosides and n-alkyl polyglycol ethers

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