Photoinduced electron transfer from triplet fullerene, 3C60, to tetracyanoethylene. Fourier transform electron paramagnetic resonance study

S. Michaeli; V. Meiklyar; M. Schulz; K. Möbius; H. Levanon

doi:10.1021/j100082a008

Photoinduced electron transfer from triplet fullerene, ³C₆₀, to tetracyanoethylene. Fourier transform electron paramagnetic resonance study

S. Michaeli, V. Meiklyar, M. Schulz, K. Möbius, H. Levanon

Radiology

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Abstract

Fourier transform EPR spectroscopy was employed in studying the electron transfer (ET) and the quenching mechanisms of the photoexcited triplet state of C₆₀ (electron donor) in the presence of the electron acceptor tetracyanoethylene (TCNE) in a benzonitrile solution. The ET reaction product, which is the stable anion radical TCNE^•-, interacts with ³C₆₀ (both detected by EPR in the liquid phase), leading to chemically induced dynamic electron polarization of TCNE^-, via triplet-doublet mixing mechanism.

Original language	English (US)
Pages (from-to)	7444-7447
Number of pages	4
Journal	Journal of physical chemistry
Volume	98
Issue number	31
DOIs	https://doi.org/10.1021/j100082a008
State	Published - Jan 1 1994

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title = "Photoinduced electron transfer from triplet fullerene, 3C60, to tetracyanoethylene. Fourier transform electron paramagnetic resonance study",

abstract = "Fourier transform EPR spectroscopy was employed in studying the electron transfer (ET) and the quenching mechanisms of the photoexcited triplet state of C60 (electron donor) in the presence of the electron acceptor tetracyanoethylene (TCNE) in a benzonitrile solution. The ET reaction product, which is the stable anion radical TCNE•-, interacts with 3C60 (both detected by EPR in the liquid phase), leading to chemically induced dynamic electron polarization of TCNE-, via triplet-doublet mixing mechanism.",

author = "S. Michaeli and V. Meiklyar and M. Schulz and K. M{\"o}bius and H. Levanon",

year = "1994",

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doi = "10.1021/j100082a008",

language = "English (US)",

volume = "98",

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journal = "Journal of physical chemistry",

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T1 - Photoinduced electron transfer from triplet fullerene, 3C60, to tetracyanoethylene. Fourier transform electron paramagnetic resonance study

AU - Michaeli, S.

AU - Meiklyar, V.

AU - Schulz, M.

AU - Möbius, K.

AU - Levanon, H.

PY - 1994/1/1

Y1 - 1994/1/1

N2 - Fourier transform EPR spectroscopy was employed in studying the electron transfer (ET) and the quenching mechanisms of the photoexcited triplet state of C60 (electron donor) in the presence of the electron acceptor tetracyanoethylene (TCNE) in a benzonitrile solution. The ET reaction product, which is the stable anion radical TCNE•-, interacts with 3C60 (both detected by EPR in the liquid phase), leading to chemically induced dynamic electron polarization of TCNE-, via triplet-doublet mixing mechanism.

AB - Fourier transform EPR spectroscopy was employed in studying the electron transfer (ET) and the quenching mechanisms of the photoexcited triplet state of C60 (electron donor) in the presence of the electron acceptor tetracyanoethylene (TCNE) in a benzonitrile solution. The ET reaction product, which is the stable anion radical TCNE•-, interacts with 3C60 (both detected by EPR in the liquid phase), leading to chemically induced dynamic electron polarization of TCNE-, via triplet-doublet mixing mechanism.

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JO - Journal of physical chemistry

JF - Journal of physical chemistry

IS - 31

ER -

Photoinduced electron transfer from triplet fullerene, ³C₆₀, to tetracyanoethylene. Fourier transform electron paramagnetic resonance study

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