Photoluminescent Mn4 single-molecule magnet

Christopher C. Beedle, Casey Stephenson, Katie J. Heroux, Wolfgang Wernsdorfer, David N. Hendrickson

Research output: Contribution to journalArticlepeer-review

55 Scopus citations

Abstract

The synthesis of [Mn4(anca)4(Hmdea) 2(mdea)2]·2CHCl3 (1) is reported along with room temperature fluorescence, UV-vis, and NMR spectra. Direct current magnetization versus field data reveal a S = 8 ground state. Quantized steps in temperature- and field-dependent magnetization versus field hysteresis loops confirm single-molecule magnet behavior.

Original languageEnglish (US)
Pages (from-to)10798-10800
Number of pages3
JournalInorganic Chemistry
Volume47
Issue number23
DOIs
StatePublished - Dec 1 2008

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