Plasmon generation in sputtered Ga-doped MgZnO thin films for solar cell applications

Vishnu Awasthi, Sushil Kumar Pandey, Vivek Garg, Brajendra S. Sengar, Pankaj Sharma, Shailendra Kumar, C. Mukherjee, Shaibal Mukherjee

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17 Scopus citations

Abstract

The crystalline, electrical, morphological, optical properties and plasmonic behaviour of Ga doped MgZnO (GMZO) thin films grown at different substrate temperatures (200-600 °C) by a dual ion beam sputtering (DIBS) system are investigated. Transmittance value of more than ∼94% in 400-1000 nm region is observed for all GMZO films. The particle plasmon features can be detected in the absorption coefficient spectra of GMZO grown at 500 and 600 °C in the form of a peak at ∼4.37 eV, which corresponds to a plasmon resonance peak of nanoclusters formed in GMZO. The presence of such plasmonic features is confirmed by ultraviolet photoelectron spectroscopy measurements. The values of particle plasmon resonance energy of various nanoclusters are in the range of solar spectrum, and these can easily be tuned and excited at the desirable wavelengths while optimizing the efficiency of solar cells (SCs) by simple alteration of DIBS growth temperature. These nanoclusters are extremely promising to enhance the optical scattering and trapping of the incident light, which increases the optical path length in the absorber layer of cost-effective SCs and eventually increases its efficiency.

Original languageEnglish (US)
Article number233101
JournalJournal of Applied Physics
Volume119
Issue number23
DOIs
StatePublished - Jun 21 2016

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