Poly(4-(aminomethyl)styrene)-b-polystyrene: Synthesis and unilamellar vesicle formation

Stefanie M. Gravano; Mark Borden; Timothy Von Werne; Edward M. Doerffler; Georgina Salazar; Aaron Chen; Edward Kisak; Joseph A. Zasadzinski; Timothy E. Patten; Marjorie L. Longo

doi:10.1021/la011309e

Poly(4-(aminomethyl)styrene)-b-polystyrene: Synthesis and unilamellar vesicle formation

Stefanie M. Gravano, Mark Borden, Timothy Von Werne, Edward M. Doerffler, Georgina Salazar, Aaron Chen, Edward Kisak, Joseph A. Zasadzinski, Timothy E. Patten, Marjorie L. Longo

Chemical Engineering and Materials Science

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Abstract

The formation of vesicles using block copolymers of the composition poly(4-(aminomethyl)styrene)-b-polystyrene was discussed. A macroinitiator was prepared by the atom transfer radical polymerization (ATRP) of (4-vinylbenzyl)phthalimide. The gel permeation chromatograms (GPC) of the block copolymers showed unimodal distributions with polydispersities of less than 1:30 and increases of molecular weights relative to the macroinitiator. The copolymer with the longest polystyrene chain yielded large vesicles indicating a large bending modulus.

Original language	English (US)
Pages (from-to)	1938-1941
Number of pages	4
Journal	Langmuir
Volume	18
Issue number	5
DOIs	https://doi.org/10.1021/la011309e
State	Published - Mar 5 2002

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title = "Poly(4-(aminomethyl)styrene)-b-polystyrene: Synthesis and unilamellar vesicle formation",

abstract = "The formation of vesicles using block copolymers of the composition poly(4-(aminomethyl)styrene)-b-polystyrene was discussed. A macroinitiator was prepared by the atom transfer radical polymerization (ATRP) of (4-vinylbenzyl)phthalimide. The gel permeation chromatograms (GPC) of the block copolymers showed unimodal distributions with polydispersities of less than 1:30 and increases of molecular weights relative to the macroinitiator. The copolymer with the longest polystyrene chain yielded large vesicles indicating a large bending modulus.",

author = "Gravano, {Stefanie M.} and Mark Borden and {Von Werne}, Timothy and Doerffler, {Edward M.} and Georgina Salazar and Aaron Chen and Edward Kisak and Zasadzinski, {Joseph A.} and Patten, {Timothy E.} and Longo, {Marjorie L.}",

year = "2002",

month = mar,

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doi = "10.1021/la011309e",

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T1 - Poly(4-(aminomethyl)styrene)-b-polystyrene

T2 - Synthesis and unilamellar vesicle formation

AU - Gravano, Stefanie M.

AU - Borden, Mark

AU - Von Werne, Timothy

AU - Doerffler, Edward M.

AU - Salazar, Georgina

AU - Chen, Aaron

AU - Kisak, Edward

AU - Zasadzinski, Joseph A.

AU - Patten, Timothy E.

AU - Longo, Marjorie L.

PY - 2002/3/5

Y1 - 2002/3/5

N2 - The formation of vesicles using block copolymers of the composition poly(4-(aminomethyl)styrene)-b-polystyrene was discussed. A macroinitiator was prepared by the atom transfer radical polymerization (ATRP) of (4-vinylbenzyl)phthalimide. The gel permeation chromatograms (GPC) of the block copolymers showed unimodal distributions with polydispersities of less than 1:30 and increases of molecular weights relative to the macroinitiator. The copolymer with the longest polystyrene chain yielded large vesicles indicating a large bending modulus.

AB - The formation of vesicles using block copolymers of the composition poly(4-(aminomethyl)styrene)-b-polystyrene was discussed. A macroinitiator was prepared by the atom transfer radical polymerization (ATRP) of (4-vinylbenzyl)phthalimide. The gel permeation chromatograms (GPC) of the block copolymers showed unimodal distributions with polydispersities of less than 1:30 and increases of molecular weights relative to the macroinitiator. The copolymer with the longest polystyrene chain yielded large vesicles indicating a large bending modulus.

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Poly(4-(aminomethyl)styrene)-b-polystyrene: Synthesis and unilamellar vesicle formation

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