Polynuclear carboxylato-bridged iron(II) clusters: Synthesis, structure, and host-guest chemistry

Sanjay K. Mandal, Victor G. Young, Lawrence Que

Research output: Contribution to journalArticlepeer-review

30 Scopus citations

Abstract

The neutral trinuclear carboxylato-bridged iron(II) complex [Fe3(O2CCH3)3(BPG)3] can, after minor structural rearrangement, bind a fourth iron(II) ion, forming the tetranuclear complex [Fe4(O2CCH3)3(BPG)3](ClO4)2. The triiron(II) complex can thus be considered as a metallacrown host for the fourth iron(II) ion.

Original languageEnglish (US)
Pages (from-to)1831-1833
Number of pages3
JournalInorganic chemistry
Volume39
Issue number8
DOIs
StatePublished - Apr 17 2000

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