Polynuclear organometal oxides: Synthesis and structure of [(η5-C5Me5)ZrCl]33-O)(μ3-OH)(μ-OH)3·2THF (THF = tetrahydrofuran)

L. M. Babcock, V. W. Day, W. G. Klemperer

Research output: Contribution to journalArticlepeer-review

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Abstract

Base hydrolysis of (η5-C5Me5)ZrCl 3 in tetrahydrofuran (THF) yields [(η5-C 5Me5)ZrCl]3(O)(OH)4·2THF which, according to X-ray structural analysis, contains a triangular Zr 3 core capped above and below by μ3-O and μ3-OH groups and edge-bridged by three μ2-OH groups.

Original languageEnglish (US)
Pages (from-to)519-520
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number8
DOIs
StatePublished - Jan 1 1988

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