Polynuclear organometal oxides: Synthesis and structure of [(η5-C5Me5)ZrCl]3(μ 3-O)(μ3-OH)(μ-OH)3·2THF (THF = tetrahydrofuran)

L. M. Babcock; V. W. Day; W. G. Klemperer

doi:10.1039/C39880000519

Polynuclear organometal oxides: Synthesis and structure of [(η⁵-C₅Me₅)ZrCl]₃(μ ₃-O)(μ₃-OH)(μ-OH)₃·2THF (THF = tetrahydrofuran)

L. M. Babcock, V. W. Day, W. G. Klemperer

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Abstract

Base hydrolysis of (η⁵-C₅Me₅)ZrCl ₃ in tetrahydrofuran (THF) yields [(η⁵-C ₅Me₅)ZrCl]₃(O)(OH)₄·2THF which, according to X-ray structural analysis, contains a triangular Zr ₃ core capped above and below by μ₃-O and μ₃-OH groups and edge-bridged by three μ₂-OH groups.

Original language	English (US)
Pages (from-to)	519-520
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/C39880000519
State	Published - 1988
Externally published	Yes

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abstract = "Base hydrolysis of (η5-C5Me5)ZrCl 3 in tetrahydrofuran (THF) yields [(η5-C 5Me5)ZrCl]3(O)(OH)4·2THF which, according to X-ray structural analysis, contains a triangular Zr 3 core capped above and below by μ3-O and μ3-OH groups and edge-bridged by three μ2-OH groups.",

author = "Babcock, {L. M.} and Day, {V. W.} and Klemperer, {W. G.}",

year = "1988",

doi = "10.1039/C39880000519",

language = "English (US)",

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journal = "Journal of the Chemical Society, Chemical Communications",

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T1 - Polynuclear organometal oxides

T2 - Synthesis and structure of [(η5-C5Me5)ZrCl]3(μ 3-O)(μ3-OH)(μ-OH)3·2THF (THF = tetrahydrofuran)

AU - Babcock, L. M.

AU - Day, V. W.

AU - Klemperer, W. G.

PY - 1988

Y1 - 1988

N2 - Base hydrolysis of (η5-C5Me5)ZrCl 3 in tetrahydrofuran (THF) yields [(η5-C 5Me5)ZrCl]3(O)(OH)4·2THF which, according to X-ray structural analysis, contains a triangular Zr 3 core capped above and below by μ3-O and μ3-OH groups and edge-bridged by three μ2-OH groups.

AB - Base hydrolysis of (η5-C5Me5)ZrCl 3 in tetrahydrofuran (THF) yields [(η5-C 5Me5)ZrCl]3(O)(OH)4·2THF which, according to X-ray structural analysis, contains a triangular Zr 3 core capped above and below by μ3-O and μ3-OH groups and edge-bridged by three μ2-OH groups.

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Polynuclear organometal oxides: Synthesis and structure of [(η⁵-C₅Me₅)ZrCl]₃(μ ₃-O)(μ₃-OH)(μ-OH)₃·2THF (THF = tetrahydrofuran)

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