Precise synthesis of polymers functionalized with anhydride moieties

Ryohei Kakuchi; Kobayashi Shingo; Kenji Sugiyama; Akira Hirao; Jianbin Zhang; Tom Hoye; Chris Macosko

Precise synthesis of polymers functionalized with anhydride moieties

Ryohei Kakuchi, Kobayashi Shingo, Kenji Sugiyama, Akira Hirao, Jianbin Zhang, Tom Hoye, Chris Macosko

Research output: Contribution to conference › Paper › peer-review

Abstract

We succeeded in preparing poly(ε-caprolactone) with hydroxyl chain end functionality by means of living ring-opening polymerization. The hydroxyl functionality at the chain end was successfully converted into anhydrous moiety via successive transformation reaction, i.e., carboxylation of hydroxyl group using maleic anhydride, introduction of conjugated diene under mitsunobu reaction, and Diels-Alder reaction of maleic anhydride and chain-end-diene group.

Original language	English (US)
Pages	352
Number of pages	1
State	Published - 2006
Event	55th SPSJ Annual Meeting - Nagoya, Japan Duration: May 24 2006 → May 26 2006

Other

Other	55th SPSJ Annual Meeting
Country/Territory	Japan
City	Nagoya
Period	5/24/06 → 5/26/06

Keywords

Anhydride
Diels-Alder reaction
End-functionalized polymer
Living polymerization
Mitsunobu reaction
Poly(ε-caprolactone)

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title = "Precise synthesis of polymers functionalized with anhydride moieties",

abstract = "We succeeded in preparing poly(ε-caprolactone) with hydroxyl chain end functionality by means of living ring-opening polymerization. The hydroxyl functionality at the chain end was successfully converted into anhydrous moiety via successive transformation reaction, i.e., carboxylation of hydroxyl group using maleic anhydride, introduction of conjugated diene under mitsunobu reaction, and Diels-Alder reaction of maleic anhydride and chain-end-diene group.",

keywords = "Anhydride, Diels-Alder reaction, End-functionalized polymer, Living polymerization, Mitsunobu reaction, Poly(ε-caprolactone)",

author = "Ryohei Kakuchi and Kobayashi Shingo and Kenji Sugiyama and Akira Hirao and Jianbin Zhang and Tom Hoye and Chris Macosko",

year = "2006",

language = "English (US)",

pages = "352",

note = "55th SPSJ Annual Meeting ; Conference date: 24-05-2006 Through 26-05-2006",

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TY - CONF

T1 - Precise synthesis of polymers functionalized with anhydride moieties

AU - Kakuchi, Ryohei

AU - Shingo, Kobayashi

AU - Sugiyama, Kenji

AU - Hirao, Akira

AU - Zhang, Jianbin

AU - Hoye, Tom

AU - Macosko, Chris

PY - 2006

Y1 - 2006

N2 - We succeeded in preparing poly(ε-caprolactone) with hydroxyl chain end functionality by means of living ring-opening polymerization. The hydroxyl functionality at the chain end was successfully converted into anhydrous moiety via successive transformation reaction, i.e., carboxylation of hydroxyl group using maleic anhydride, introduction of conjugated diene under mitsunobu reaction, and Diels-Alder reaction of maleic anhydride and chain-end-diene group.

AB - We succeeded in preparing poly(ε-caprolactone) with hydroxyl chain end functionality by means of living ring-opening polymerization. The hydroxyl functionality at the chain end was successfully converted into anhydrous moiety via successive transformation reaction, i.e., carboxylation of hydroxyl group using maleic anhydride, introduction of conjugated diene under mitsunobu reaction, and Diels-Alder reaction of maleic anhydride and chain-end-diene group.

KW - Anhydride

KW - Diels-Alder reaction

KW - End-functionalized polymer

KW - Living polymerization

KW - Mitsunobu reaction

KW - Poly(ε-caprolactone)

UR - http://www.scopus.com/inward/record.url?scp=33749658235&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33749658235&partnerID=8YFLogxK

M3 - Paper

AN - SCOPUS:33749658235

SP - 352

T2 - 55th SPSJ Annual Meeting

Y2 - 24 May 2006 through 26 May 2006

ER -

Precise synthesis of polymers functionalized with anhydride moieties

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