Preparation and characterization of decatungstomolybdoniobogermanic heteropoly acid H5[GeW10MoNbO40] · 20H2O

Qingyin Wu, Shukun Wang, D Li, Xufeng Xie

Research output: Contribution to journalArticlepeer-review

23 Scopus citations

Abstract

The decatungstomolybdoniobogermanic heteropoly acid H5[GeW10MoNbO40]·20H2O has been prepared for the first time. The optimal proportion of the solutions of the component and the pH of the synthesis reaction are given. The product was characterized by chemical analysis, conductometric and potentiometric titration, IR, UV, XRD, 183W NMR and TG-DTA. The IR, UV, XRD and 183WW NMR indicate that H5[GeW10MoNbO40]·20H2O possesses the Keggin structure. The TG-DTA curve shows the sequence of water loss in the acid, the amount of the loss as well as the thermostability of the acid.

Original languageEnglish (US)
Pages (from-to)308-311
Number of pages4
JournalInorganic Chemistry Communications
Volume5
Issue number5
DOIs
StatePublished - 2002

Bibliographical note

Funding Information:
The financial support from the China Postdoctoral Science Foundation and the Natural Science Foundation of Zhejiang University for this work is greatly appreciated.

Copyright:
Copyright 2008 Elsevier B.V., All rights reserved.

Keywords

  • Characterization
  • Deca-tungstomolybdoniobogermanic acid
  • Heteropoly acid
  • Preparation

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