Preparation and reactivity of polymer-supported 2-iodylphenol ethers, an efficient recyclable oxidizing system

Rashad R. Karimov, Zeinul Gabiden M. Kazhkenov, Matthew J. Modjewski, Eric M. Peterson, Viktor Zhdankin

Research output: Contribution to journalArticlepeer-review

28 Scopus citations

Abstract

(Chemical Equation Presented) Preparation of new recyclable polymer-supported oxidizing reagents based on 2-iodylphenol ethers is described. The synthesis employs commercially available aminomethylated polystyrene or Merrifield resin and affords polymer-supported 2-iodylphenol ethers with loading up to 0.86 mmol/g with respect to IO2 groups. The new reagents effect clean and efficient conversion of a wide range of alcohols, including heteroatomic and unsaturated structures, to the corresponding carbonyl compounds. Recycling of the resins is possible with minimal loss of activity after several reoxidations.

Original languageEnglish (US)
Pages (from-to)8149-8151
Number of pages3
JournalJournal of Organic Chemistry
Volume72
Issue number21
DOIs
StatePublished - Oct 12 2007

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