Rational synthesis for all All-homocalixarenes

Alexander V. Predeus; Vijay Gopalsamuthiram; Richard J. Staples; William D. Wulff

doi:10.1002/anie.201206785

Rational synthesis for all All-homocalixarenes

Alexander V. Predeus, Vijay Gopalsamuthiram, Richard J. Staples, William D. Wulff

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Have it all: The synthesis of homocalixarenes of all sizes has been demonstrated using the triple annulation of bis(carbene) complexes with diynes (see scheme). This strategy in principle should allow access to all homocalixarenes. The generality of the synthetic approach is also demonstrated by the preparation of a pyrrole-containing calixarene.

Original language	English (US)
Pages (from-to)	911-915
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	3
DOIs	https://doi.org/10.1002/anie.201206785
State	Published - Jan 14 2013

Keywords

annulation
calixarenes
carbenes
macrocycles
synthetic methods

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abstract = "Have it all: The synthesis of homocalixarenes of all sizes has been demonstrated using the triple annulation of bis(carbene) complexes with diynes (see scheme). This strategy in principle should allow access to all homocalixarenes. The generality of the synthetic approach is also demonstrated by the preparation of a pyrrole-containing calixarene.",

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KW - macrocycles

KW - synthetic methods

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Rational synthesis for all All-homocalixarenes

Abstract

Keywords

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