Relative and absolute stereochemistry of the didemnaketals, metabolites of a Palauan ascidian, Didemnum sp.

Christine E. Salomon; David H. Williams; Emil Lobkovsky; Jon C. Clardy; D. John Faulkner

doi:10.1021/ol025904z

Relative and absolute stereochemistry of the didemnaketals, metabolites of a Palauan ascidian, Didemnum sp.

Christine E. Salomon, David H. Williams, Emil Lobkovsky, Jon C. Clardy, D. John Faulkner

Center for Drug Design

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Abstract

Matrix presented The absolute stereochemistry of the heptaprenoids didemnaketals B (2) and C (3), isolated from a Palauan ascidian, was determined using a combination of degradation and derivatization experiments, chiral shift methods, and comparison of fragments to known compounds.

Original language	English (US)
Pages (from-to)	1699-1702
Number of pages	4
Journal	Organic Letters
Volume	4
Issue number	10
DOIs	https://doi.org/10.1021/ol025904z
State	Published - May 16 2002

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title = "Relative and absolute stereochemistry of the didemnaketals, metabolites of a Palauan ascidian, Didemnum sp.",

abstract = "Matrix presented The absolute stereochemistry of the heptaprenoids didemnaketals B (2) and C (3), isolated from a Palauan ascidian, was determined using a combination of degradation and derivatization experiments, chiral shift methods, and comparison of fragments to known compounds.",

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T1 - Relative and absolute stereochemistry of the didemnaketals, metabolites of a Palauan ascidian, Didemnum sp.

AU - Salomon, Christine E.

AU - Williams, David H.

AU - Lobkovsky, Emil

AU - Clardy, Jon C.

AU - Faulkner, D. John

PY - 2002/5/16

Y1 - 2002/5/16

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AB - Matrix presented The absolute stereochemistry of the heptaprenoids didemnaketals B (2) and C (3), isolated from a Palauan ascidian, was determined using a combination of degradation and derivatization experiments, chiral shift methods, and comparison of fragments to known compounds.

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Relative and absolute stereochemistry of the didemnaketals, metabolites of a Palauan ascidian, Didemnum sp.

Abstract

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