Resonance Raman evidence for the interconversion between an [Fe(III)-η1-OOH]2+ and [Fe(III)-η2-O2]+ species and mechanistic implications thereof

Raymond Y.N. Ho; Gerard Roelfes; Roel Hermant; Ronald Hage; Ben L. Feringa; Lawrence Que

doi:10.1039/a905535e

Resonance Raman evidence for the interconversion between an [Fe(III)-η¹-OOH]²⁺ and [Fe(III)-η²-O₂]⁺ species and mechanistic implications thereof

Raymond Y.N. Ho, Gerard Roelfes, Roel Hermant, Ronald Hage, Ben L. Feringa, Lawrence Que

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

80 Scopus citations

Abstract

The deprotonation of [Fe(III)(N4Py)(η¹-OOH)]²⁺ 1 gives [Fe(III)(N4Py)(η²-OO)]⁺ 2, as unequivocally demonstrated by resonance Raman spectroscopy, and leads to the loss of alkane hydroxylation activity by 1.

Original language	English (US)
Pages (from-to)	2161-2162
Number of pages	2
Journal	Chemical Communications
Issue number	21
DOIs	https://doi.org/10.1039/a905535e
State	Published - Nov 7 1999

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abstract = "The deprotonation of [Fe(III)(N4Py)(η1-OOH)]2+ 1 gives [Fe(III)(N4Py)(η2-OO)]+ 2, as unequivocally demonstrated by resonance Raman spectroscopy, and leads to the loss of alkane hydroxylation activity by 1.",

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AU - Roelfes, Gerard

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AU - Hage, Ronald

AU - Feringa, Ben L.

AU - Que, Lawrence

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AB - The deprotonation of [Fe(III)(N4Py)(η1-OOH)]2+ 1 gives [Fe(III)(N4Py)(η2-OO)]+ 2, as unequivocally demonstrated by resonance Raman spectroscopy, and leads to the loss of alkane hydroxylation activity by 1.

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