Resonance Raman evidence for the interconversion between an [Fe(III)-η1-OOH]2+ and [Fe(III)-η2-O2]+ species and mechanistic implications thereof

Raymond Y.N. Ho, Gerard Roelfes, Roel Hermant, Ronald Hage, Ben L. Feringa, Lawrence Que

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Abstract

The deprotonation of [Fe(III)(N4Py)(η1-OOH)]2+ 1 gives [Fe(III)(N4Py)(η2-OO)]+ 2, as unequivocally demonstrated by resonance Raman spectroscopy, and leads to the loss of alkane hydroxylation activity by 1.

Original languageEnglish (US)
Pages (from-to)2161-2162
Number of pages2
JournalChemical Communications
Issue number21
DOIs
StatePublished - Nov 7 1999

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