Reversible, Stepwise Addition of 1,2-Diester-Substituted Alkenes to Ru2[(CH3)2PCH2P(CH3)2]2(CO)5. Crystal and Molecular Structure of the Diruthenacyclobutane Complex Ru2[(CH3)2PCH2P(CH3)2]2(CO)4[μ-η1:η1-C2(H)2(CO2CH3)2]•C7H8

Kimberly A. Johnson; Wayne L. Gladfelter

doi:10.1021/om00048a004

Reversible, Stepwise Addition of 1,2-Diester-Substituted Alkenes to Ru₂[(CH₃)₂PCH₂P(CH₃)₂]₂(CO)₅. Crystal and Molecular Structure of the Diruthenacyclobutane Complex Ru₂[(CH₃)₂PCH₂P(CH₃)₂]₂(CO)₄[μ-η¹:η¹-C₂(H)₂(CO₂CH₃)₂]•C₇H₈

Kimberly A. Johnson, Wayne L. Gladfelter

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

cis- and trans-Diester-substituted alkenes react with Ru₂(dmpm)₂(CO)₅ (dmpm = bis(dimethyl-phosphino)methane) to form the trans-substituted diruthenacyclobutane. This process was shown to be stepwise and reversible, and a zwitterionic intermediate is proposed.

Original language	English (US)
Pages (from-to)	376-378
Number of pages	3
Journal	Organometallics
Volume	10
Issue number	2
DOIs	https://doi.org/10.1021/om00048a004
State	Published - Feb 1 1991

Access

10.1021/om00048a004

OpenUrl availability

Full text

Fingerprint

Dive into the research topics of 'Reversible, Stepwise Addition of 1,2-Diester-Substituted Alkenes to Ru₂[(CH₃)₂PCH₂P(CH₃)₂]₂(CO)₅. Crystal and Molecular Structure of the Diruthenacyclobutane Complex Ru₂[(CH₃)₂PCH₂P(CH₃)₂]₂(CO)₄[μ-η¹:η¹-C₂(H)₂(CO₂CH₃)₂]•C₇H₈'. Together they form a unique fingerprint.

Cite this

Reversible, Stepwise Addition of 1,2-Diester-Substituted Alkenes to Ru₂[(CH₃)₂PCH₂P(CH₃)₂]₂(CO)₅. Crystal and Molecular Structure of the Diruthenacyclobutane Complex Ru₂[(CH₃)₂PCH₂P(CH₃)₂]₂(CO)₄[μ-η¹:η¹-C₂(H)₂(CO₂CH₃)₂]•C₇H₈. / Johnson, Kimberly A.; Gladfelter, Wayne L.
In: Organometallics, Vol. 10, No. 2, 01.02.1991, p. 376-378.

Research output: Contribution to journal › Article › peer-review

@article{538877776bba40a6b246878734ada99e,

title = "Reversible, Stepwise Addition of 1,2-Diester-Substituted Alkenes to Ru2[(CH3)2PCH2P(CH3)2]2(CO)5. Crystal and Molecular Structure of the Diruthenacyclobutane Complex Ru2[(CH3)2PCH2P(CH3)2]2(CO)4[μ-η1:η1-C2(H)2(CO2CH3)2]•C7H8",

abstract = "cis- and trans-Diester-substituted alkenes react with Ru2(dmpm)2(CO)5 (dmpm = bis(dimethyl-phosphino)methane) to form the trans-substituted diruthenacyclobutane. This process was shown to be stepwise and reversible, and a zwitterionic intermediate is proposed.",

author = "Johnson, {Kimberly A.} and Gladfelter, {Wayne L.}",

year = "1991",

month = feb,

day = "1",

doi = "10.1021/om00048a004",

language = "English (US)",

volume = "10",

pages = "376--378",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "2",

}

TY - JOUR

T1 - Reversible, Stepwise Addition of 1,2-Diester-Substituted Alkenes to Ru2[(CH3)2PCH2P(CH3)2]2(CO)5. Crystal and Molecular Structure of the Diruthenacyclobutane Complex Ru2[(CH3)2PCH2P(CH3)2]2(CO)4[μ-η1:η1-C2(H)2(CO2CH3)2]•C7H8

AU - Johnson, Kimberly A.

AU - Gladfelter, Wayne L.

PY - 1991/2/1

Y1 - 1991/2/1

N2 - cis- and trans-Diester-substituted alkenes react with Ru2(dmpm)2(CO)5 (dmpm = bis(dimethyl-phosphino)methane) to form the trans-substituted diruthenacyclobutane. This process was shown to be stepwise and reversible, and a zwitterionic intermediate is proposed.

AB - cis- and trans-Diester-substituted alkenes react with Ru2(dmpm)2(CO)5 (dmpm = bis(dimethyl-phosphino)methane) to form the trans-substituted diruthenacyclobutane. This process was shown to be stepwise and reversible, and a zwitterionic intermediate is proposed.

UR - http://www.scopus.com/inward/record.url?scp=0038624467&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0038624467&partnerID=8YFLogxK

U2 - 10.1021/om00048a004

DO - 10.1021/om00048a004

M3 - Article

AN - SCOPUS:0038624467

SN - 0276-7333

VL - 10

SP - 376

EP - 378

JO - Organometallics

JF - Organometallics

IS - 2

ER -