Abstract
In the last decades, metallopolymers have received great attention due to their various applications in the fields of materials and chemistry. In this article, a neutral 18-electron exo-substituted η4-cyclopentadiene CpCo(I) unit-containing polymer is prepared in a controlled/"living" fashion by combining facile click chemistry and ring-opening metathesis polymerization (ROMP). This Co(I)-containing polymer is further used as a heterogeneous macromolecular catalyst for atom transfer radical polymerization (ATRP) of methyl methacrylate and styrene. By combining facile click chemistry and ring-opening metathesis polymerization (ROMP), a neutral 18-electron exo-substituted η4-cyclopentadiene CpCo(I) unit-containing polymer is prepared in a controlled/"living" fashion. This Co(I)-containing polymer is further used as a heterogeneous macromolecular catalyst for atom transfer radical polymerization (ATRP) of methyl methacrylate and styrene.
Original language | English (US) |
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Pages (from-to) | 1840-1845 |
Number of pages | 6 |
Journal | Macromolecular Rapid Communications |
Volume | 35 |
Issue number | 21 |
DOIs | |
State | Published - Nov 1 2014 |
Externally published | Yes |
Bibliographical note
Publisher Copyright:© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Keywords
- ATRP
- ROMP
- heterogeneous catalyst
- metallocene