Simple (imidazol-2-ylidene)-Pd-acetate complexes as effective precatalysts for sterically hindered suzuki-miyaura couplings

Rohit Singh, Mihai S. Viciu, Natalia Kramareva, Oscar Navarro, Steven P. Nolan

Research output: Contribution to journalArticlepeer-review

197 Scopus citations

Abstract

(Chemical Equation Presented) A simplified synthesis of N-heterocyclic carbene (NHC)Pd-carboxylate complexes and their activity in Suzuki-Miyaura cross-coupling reactions are described. Coupling of sterically hindered aryl and activated alkyl chlorides bearing β-hydrogens has been successfully achieved.

Original languageEnglish (US)
Pages (from-to)1829-1832
Number of pages4
JournalOrganic Letters
Volume7
Issue number9
DOIs
StatePublished - Apr 28 2005
Externally publishedYes

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