Soft synthesis of isocyanate-functionalised metal-organic frameworks

Jenny G. Vitillo; Tristan Lescouet; Marie Savonnet; David Farrusseng; Silvia Bordiga

doi:10.1039/c2dt31977b

Soft synthesis of isocyanate-functionalised metal-organic frameworks

Jenny G. Vitillo, Tristan Lescouet, Marie Savonnet, David Farrusseng, Silvia Bordiga

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

We have developed an original synthetic pathway for the conversion of a MIL-68(In)-NH₂ metal-organic framework into its corresponding isocyanate (-NCO) derivative. This two-step soft post-modification technique leads to highly porous isostructural materials.

Original language	English (US)
Pages (from-to)	14236-14238
Number of pages	3
Journal	Dalton Transactions
Volume	41
Issue number	47
DOIs	https://doi.org/10.1039/c2dt31977b
State	Published - Dec 21 2012

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title = "Soft synthesis of isocyanate-functionalised metal-organic frameworks",

abstract = "We have developed an original synthetic pathway for the conversion of a MIL-68(In)-NH2 metal-organic framework into its corresponding isocyanate (-NCO) derivative. This two-step soft post-modification technique leads to highly porous isostructural materials.",

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T1 - Soft synthesis of isocyanate-functionalised metal-organic frameworks

AU - Vitillo, Jenny G.

AU - Lescouet, Tristan

AU - Savonnet, Marie

AU - Farrusseng, David

AU - Bordiga, Silvia

PY - 2012/12/21

Y1 - 2012/12/21

N2 - We have developed an original synthetic pathway for the conversion of a MIL-68(In)-NH2 metal-organic framework into its corresponding isocyanate (-NCO) derivative. This two-step soft post-modification technique leads to highly porous isostructural materials.

AB - We have developed an original synthetic pathway for the conversion of a MIL-68(In)-NH2 metal-organic framework into its corresponding isocyanate (-NCO) derivative. This two-step soft post-modification technique leads to highly porous isostructural materials.

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Soft synthesis of isocyanate-functionalised metal-organic frameworks

Abstract

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