Abstract
Direct cyclopalladation of benzyl methyl sulfide, benzyl phenyl sulfide and 1,3-bis(methylthiomethyl)benzene using Pd(OAc) 2 can be accomplished using silica gel instead of a solvent. The yields of the corresponding cyclopalladated complexes in these green transformations are very similar to those obtained using conventional solvent conditions. The X-ray crystallographic data for trans-Pd(HL) 2Cl 2 (HL = benzyl methyl sulfide) are reported.
Original language | English (US) |
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Pages (from-to) | 64-65 |
Number of pages | 2 |
Journal | Inorganic Chemistry Communications |
Volume | 26 |
DOIs | |
State | Published - Dec 2012 |
Externally published | Yes |
Keywords
- C,S-palladacycle
- Cyclopalladation of sulfides
- Reactions on silica gel
- S,C,S-palladacycle