TY - JOUR
T1 - Solvent-free synthesis of zeolites from solid raw materials
AU - Ren, Limin
AU - Wu, Qinming
AU - Yang, Chengguang
AU - Zhu, Longfeng
AU - Li, Caijin
AU - Zhang, Pengling
AU - Zhang, Haiyan
AU - Meng, Xiangju
AU - Xiao, Feng Shou
PY - 2012/9/19
Y1 - 2012/9/19
N2 - As important industrial materials, microporous zeolites are necessarily synthesized in the presence of solvents such as in hydrothermal, solvothermal, and ionothermal routes. We demonstrate here a simple and generalized solvent-free route for synthesizing various types of zeolites by mixing, grinding, and heating solid raw materials. Compared with conventional hydrothermal route, the avoidance of solvents in the synthesis not only significantly reduces the waste production, but also greatly increases the yield of zeolite products. In addition, the use of starting solid raw materials remarkably enhances the synthesis efficiency and reduces the use of raw materials, energy, and costs.
AB - As important industrial materials, microporous zeolites are necessarily synthesized in the presence of solvents such as in hydrothermal, solvothermal, and ionothermal routes. We demonstrate here a simple and generalized solvent-free route for synthesizing various types of zeolites by mixing, grinding, and heating solid raw materials. Compared with conventional hydrothermal route, the avoidance of solvents in the synthesis not only significantly reduces the waste production, but also greatly increases the yield of zeolite products. In addition, the use of starting solid raw materials remarkably enhances the synthesis efficiency and reduces the use of raw materials, energy, and costs.
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U2 - 10.1021/ja3044954
DO - 10.1021/ja3044954
M3 - Article
AN - SCOPUS:84866480638
SN - 0002-7863
VL - 134
SP - 15173
EP - 15176
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 37
ER -