Stereoselective synthesis of the C7-C21 segment of epothilone A via asymmetric alkoxyallyl- and crotylboration

P. Veeraraghavan Ramachandran, Bodhuri Prabhudas, Debarshi Pratihar, J. Subash Chandra, M. Venkat Ram Reddy

Research output: Contribution to journalArticlepeer-review

22 Scopus citations

Abstract

The synthesis of the C7-C21 fragment of epothilone A involving asymmetric alkoxyallyl- and crotylboration using α-pinene-derived reagents is described.

Original languageEnglish (US)
Pages (from-to)3745-3748
Number of pages4
JournalTetrahedron Letters
Volume44
Issue number19
DOIs
StatePublished - May 5 2003

Bibliographical note

Funding Information:
Financial support from the Herbert C. Brown Center for Borane Research and Aldrich Chemical Company is greatly acknowledged.

Keywords

  • Alkoxyallylboration
  • Crotylboration
  • Epothilone
  • Wittig reaction
  • α-pinene

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