Stereospecific alkane hydroxylation by non-heme iron catalysts: Mechanistic evidence for an Fe^v=O active species

Engineering & Materials Science

• Hydroxylation 100%
• Ligands 73%
• Paraffins 63%
• Iron 49%
• Catalysts 46%
• Oxidants 28%
• Enzymes 25%
• Oxidation 19%
• Oxygen 17%
• Electronic properties 17%
• Hydrogen bonds 15%
• Isotopes 13%
• Amines 13%
• Alcohols 12%
• Electrons 11%
• Labeling 10%
• Methane 10%
• Chemical activation 9%
• Hydrocarbons 9%
• Substrates 7%
• Water 5%

Medicine & Life Sciences

• Alkanes 83%
• Hydroxylation 63%
• Iron 46%
• Ligands 39%
• tris(2-pyridylmethyl)amine 27%
• Heme 24%
• Oxidants 23%
• methane monooxygenase 20%
• Isotope Labeling 16%
• Dioxygenases 15%
• Oxygen 15%
• Hydrocarbons 14%
• Hydrogen Bonding 13%
• hydroxide ion 12%
• Enzymes 12%
• Electrons 8%
• Alcohols 8%
• Water 7%

Chemical Compounds

• Alkane 46%
• Ligand 24%
• Catalyst 22%
• Heme 20%
• Epimerization 13%
• Environment 12%
• Spin State 12%
• Tautomerization 11%
• Dioxygen 10%
• Tris 9%
• Electronic Property 9%
• Hydroxide 8%
• Methane 8%
• Cleavage 7%
• Amine 7%
• Strength 7%
• Hydrogen Bond 6%
• Alcohol 6%
• Electron Particle 5%
• Oxidation Reaction 4%