Sterically Crowded Gallium Amidinate Complexes

Samuel Dagorne, Richard F. Jordan, Victor G Young

Research output: Contribution to journalArticlepeer-review

48 Scopus citations

Abstract

The sterically crowded gallium amidinate complexes {tBuC(NR′)2}GaX2 (X = Cl, Me, Et, CH2Ph; R′ = iPr, Cy, tBu) have been synthesized in good yield. X-ray crystallographic analyses show that the steric interactions between the tBu and R′ groups influence the R′-N-Ga angle and the steric environment at gallium.

Original languageEnglish (US)
Pages (from-to)4619-4623
Number of pages5
JournalOrganometallics
Volume18
Issue number22
DOIs
StatePublished - Oct 25 1999

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