Studies toward the syntheses of functionalized, fluorinated allyl alcohols

P. V. Ramachandran; M. Venkat Ram Reddy; Michael T. Rudd

Studies toward the syntheses of functionalized, fluorinated allyl alcohols

P. V. Ramachandran, M. Venkat Ram Reddy, Michael T. Rudd

Chemistry & Biochemistry

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Abstract

This chapter reviews our study of Morita-Baylis-Hillman (MBH) and vinylmetalation reactions for the synthesis of achiral and chiral, functionalized, fluorinated allyl alcohols. Vinylmetalation of fluoro-carbonyls with aluminum and copper reagents for the synthesis of unsubstituted, and β-substituted fluorinated allyl alcohols is summarized. An exploratory study of terpenyl alcohols as chiral auxiliaries in these reactions is also discussed.

Original language	English (US)
Pages (from-to)	117-126
Number of pages	10
Journal	ACS Symposium Series
Volume	746
State	Published - Dec 1 1999

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Studies toward the syntheses of functionalized, fluorinated allyl alcohols

Abstract

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