Studies toward the syntheses of functionalized, fluorinated allyl alcohols

P. V. Ramachandran, M. Venkat Ram Reddy, Michael T. Rudd

Research output: Contribution to journalArticlepeer-review

Abstract

This chapter reviews our study of Morita-Baylis-Hillman (MBH) and vinylmetalation reactions for the synthesis of achiral and chiral, functionalized, fluorinated allyl alcohols. Vinylmetalation of fluoro-carbonyls with aluminum and copper reagents for the synthesis of unsubstituted, and β-substituted fluorinated allyl alcohols is summarized. An exploratory study of terpenyl alcohols as chiral auxiliaries in these reactions is also discussed.

Original languageEnglish (US)
Pages (from-to)117-126
Number of pages10
JournalACS Symposium Series
Volume746
StatePublished - Dec 1 1999

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