Study of solute retention in reversed-phase high-performance liquid chromatography on hydrocarbonaceous and three fluorinated bonded phases

Paul C. Sadek, Peter W Carr

Research output: Contribution to journalArticlepeer-review

74 Scopus citations

Abstract

The retention properties of three fluorinated reversed-phase high-performance liquid chromatography bonded phases were characterized through the use of a wide variety of substituted aromatic test solutes. An identical study was conducted on a hydrocarbonaceous decyl bonded phase enabling the direct comparison of all phases. Functional groups were found to affect retention in a fundamentally different way on each of these bonded phases. Fluorinated alcohols were used as organic mobile phase modifiers and compared with the non-fluorinated alcohol modifiers through their effects on solute retention.

Original languageEnglish (US)
Pages (from-to)25-41
Number of pages17
JournalJournal of Chromatography A
Volume288
Issue numberC
DOIs
StatePublished - 1984

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