TY - JOUR
T1 - Synthese von 3H‐1,2,3,4‐Triazametallol‐Komplexen durch Addition von Azidoameisensäure‐methylester an die Metall – Kohlenstoff‐Dreifachbindung Cyclopentadienyl‐substituierter Carbin‐Komplexe von Molybdän und Wolfram
AU - Stegmair, Claudia M.
AU - Ullrich, Waltraud
AU - Schütt, Wolfgang
AU - Kiprof, Paul
AU - Kreißl, Fritz R.
PY - 1992/7
Y1 - 1992/7
N2 - Synthesis of 3H‐1,2,3,4‐Triazametallole Complexes by the Addition of Methyl Azidoformate to the Metal–Carbon Triple Bond of Cyclopentadienyl‐Substituted Carbyne Complexes of Molybdenum and Tungsten N3CO2Me attacks the electron‐rich metal–carbon triple bond in C5H5(CO)2 ‐ n (PMe3)nMCR (M = Mo, W; R = Ph, Tol; n = 0, 1) (1) to provide neutral 3H‐1,2,3,4‐Triazametallole complexes 2.
AB - Synthesis of 3H‐1,2,3,4‐Triazametallole Complexes by the Addition of Methyl Azidoformate to the Metal–Carbon Triple Bond of Cyclopentadienyl‐Substituted Carbyne Complexes of Molybdenum and Tungsten N3CO2Me attacks the electron‐rich metal–carbon triple bond in C5H5(CO)2 ‐ n (PMe3)nMCR (M = Mo, W; R = Ph, Tol; n = 0, 1) (1) to provide neutral 3H‐1,2,3,4‐Triazametallole complexes 2.
KW - 3H‐1,2,3,4‐Triazametalloles
KW - Carbene complexes
KW - Carbyne complexes
KW - Molybdenum complexes
KW - Tungsten complexes
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U2 - 10.1002/cber.19921250710
DO - 10.1002/cber.19921250710
M3 - Article
AN - SCOPUS:0009877938
SN - 0009-2940
VL - 125
SP - 1571
EP - 1573
JO - Chemische Berichte
JF - Chemische Berichte
IS - 7
ER -