Synthesis and Characterization of the Linear Trinuclear Complexes [M 3II(O2CCH3)6(biphme)2], M = Mn, Fe

R. Lynn Rardin, Avi Bino, Peter Poganiuch, William B Tolman, Shuncheng Liu, Stephen J. Lippard

Research output: Contribution to journalArticlepeer-review

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Abstract

A Mn3 chain bridged by four bidentate and two monodentate carboxylate ligands characterizes the MnII title complex 1. Unique features are the monodentate acetate bridges, which have a “dangling” oxygen atom that influences the molecular structure through weak interactions with the terminal Mn atoms. (Figure Presented.)

Original languageEnglish (US)
Pages (from-to)812-814
Number of pages3
JournalAngewandte Chemie International Edition in English
Volume29
Issue number7
DOIs
StatePublished - Jul 1990

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