Synthesis and mass spectra of furylcyclopropyl and furfurylidene ketones

V. I. Kadentsev; V. D. Sokovykh; O. S. Chizhov; V. M. Shostakovskii; Robert M Carlson

doi:10.1007/BF00958811

Synthesis and mass spectra of furylcyclopropyl and furfurylidene ketones

V. I. Kadentsev, V. D. Sokovykh, O. S. Chizhov, V. M. Shostakovskii, Robert M Carlson

Chemistry & Biochemistry

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Abstract

1. The reaction of furfurylidene ketones with dimethylsulfoxonium methylide leads to the formation of furylcyclopropyl ketones in about 90% yield. 2. Reaction of both the cyclopropane ring and the double bond with the furan ring, leading to the formation of aromatic hydrocarbon ions, occurs in the dissociative ionization upon electron impact of the furylcyclopropyl and furfurylidene ketones.

Original language	English (US)
Pages (from-to)	934-938
Number of pages	5
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	29
Issue number	6
DOIs	https://doi.org/10.1007/BF00958811
State	Published - Jun 1 1980

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title = "Synthesis and mass spectra of furylcyclopropyl and furfurylidene ketones",

abstract = "1. The reaction of furfurylidene ketones with dimethylsulfoxonium methylide leads to the formation of furylcyclopropyl ketones in about 90% yield. 2. Reaction of both the cyclopropane ring and the double bond with the furan ring, leading to the formation of aromatic hydrocarbon ions, occurs in the dissociative ionization upon electron impact of the furylcyclopropyl and furfurylidene ketones.",

author = "Kadentsev, {V. I.} and Sokovykh, {V. D.} and Chizhov, {O. S.} and Shostakovskii, {V. M.} and Carlson, {Robert M}",

year = "1980",

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T1 - Synthesis and mass spectra of furylcyclopropyl and furfurylidene ketones

AU - Kadentsev, V. I.

AU - Sokovykh, V. D.

AU - Chizhov, O. S.

AU - Shostakovskii, V. M.

AU - Carlson, Robert M

PY - 1980/6/1

Y1 - 1980/6/1

N2 - 1. The reaction of furfurylidene ketones with dimethylsulfoxonium methylide leads to the formation of furylcyclopropyl ketones in about 90% yield. 2. Reaction of both the cyclopropane ring and the double bond with the furan ring, leading to the formation of aromatic hydrocarbon ions, occurs in the dissociative ionization upon electron impact of the furylcyclopropyl and furfurylidene ketones.

AB - 1. The reaction of furfurylidene ketones with dimethylsulfoxonium methylide leads to the formation of furylcyclopropyl ketones in about 90% yield. 2. Reaction of both the cyclopropane ring and the double bond with the furan ring, leading to the formation of aromatic hydrocarbon ions, occurs in the dissociative ionization upon electron impact of the furylcyclopropyl and furfurylidene ketones.

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JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 6

ER -

Synthesis and mass spectra of furylcyclopropyl and furfurylidene ketones

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