Synthesis and x-ray crystallography of chiral tropocoronands

Philip J. Chenier; Jason A. Halfen; Tami L. Raguse; Autumn E. Rich; Kathryn E. Splan; Kazuki Yoshioka; Thomas R. Hoye

doi:10.1081/SCC-100000574

Synthesis and x-ray crystallography of chiral tropocoronands

Philip J. Chenier, Jason A. Halfen, Tami L. Raguse, Autumn E. Rich, Kathryn E. Splan, Kazuki Yoshioka, Thomas R. Hoye

Chemistry (Twin Cities)

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Abstract

The synthesis of several chiral tropocoronands (6 and 7) has been accomplished. These compounds have been shown to complex with various metals. Tropocoronands that have been synthesized include H₂(TC-3, cyhex) through H₂(TC-6, cyhex) (6) and H₂ (TC-3, diphen) through H₂(TC-6, diphen) (7). The route is short and the tropocoronands are easily purified by chromatography or recrystallization. Two other groups have been incorporated into tropocoronands, H₂(TC-3, binap) (9) and H₂(TC-6, pent) (10).

Original language	English (US)
Pages (from-to)	487-503
Number of pages	17
Journal	Synthetic Communications
Volume	31
Issue number	4
DOIs	https://doi.org/10.1081/SCC-100000574
State	Published - 2001

Bibliographical note

Funding Information:
This research was supported in part by the donors of the Petroleum Research Fund, and administered by the American Chemical Society; Research Corporation; the University of Wisconsin–Eau Claire; and the National Institutes of Health.

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title = "Synthesis and x-ray crystallography of chiral tropocoronands",

abstract = "The synthesis of several chiral tropocoronands (6 and 7) has been accomplished. These compounds have been shown to complex with various metals. Tropocoronands that have been synthesized include H2(TC-3, cyhex) through H2(TC-6, cyhex) (6) and H2 (TC-3, diphen) through H2(TC-6, diphen) (7). The route is short and the tropocoronands are easily purified by chromatography or recrystallization. Two other groups have been incorporated into tropocoronands, H2(TC-3, binap) (9) and H2(TC-6, pent) (10).",

author = "Chenier, {Philip J.} and Halfen, {Jason A.} and Raguse, {Tami L.} and Rich, {Autumn E.} and Splan, {Kathryn E.} and Kazuki Yoshioka and Hoye, {Thomas R.}",

note = "Funding Information: This research was supported in part by the donors of the Petroleum Research Fund, and administered by the American Chemical Society; Research Corporation; the University of Wisconsin–Eau Claire; and the National Institutes of Health.",

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T1 - Synthesis and x-ray crystallography of chiral tropocoronands

AU - Chenier, Philip J.

AU - Halfen, Jason A.

AU - Raguse, Tami L.

AU - Rich, Autumn E.

AU - Splan, Kathryn E.

AU - Yoshioka, Kazuki

AU - Hoye, Thomas R.

N1 - Funding Information: This research was supported in part by the donors of the Petroleum Research Fund, and administered by the American Chemical Society; Research Corporation; the University of Wisconsin–Eau Claire; and the National Institutes of Health.

PY - 2001

Y1 - 2001

N2 - The synthesis of several chiral tropocoronands (6 and 7) has been accomplished. These compounds have been shown to complex with various metals. Tropocoronands that have been synthesized include H2(TC-3, cyhex) through H2(TC-6, cyhex) (6) and H2 (TC-3, diphen) through H2(TC-6, diphen) (7). The route is short and the tropocoronands are easily purified by chromatography or recrystallization. Two other groups have been incorporated into tropocoronands, H2(TC-3, binap) (9) and H2(TC-6, pent) (10).

AB - The synthesis of several chiral tropocoronands (6 and 7) has been accomplished. These compounds have been shown to complex with various metals. Tropocoronands that have been synthesized include H2(TC-3, cyhex) through H2(TC-6, cyhex) (6) and H2 (TC-3, diphen) through H2(TC-6, diphen) (7). The route is short and the tropocoronands are easily purified by chromatography or recrystallization. Two other groups have been incorporated into tropocoronands, H2(TC-3, binap) (9) and H2(TC-6, pent) (10).

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JO - Synthetic Communications

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IS - 4

ER -

Synthesis and x-ray crystallography of chiral tropocoronands

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