Abstract
Magnets with a low-temperature coefficient of coercivity (TCC) have various applications in a varying temperature environment. Rare-earth magnets like NdFeB are widely used, but they usually have a large negative TCC. Here, it is first experimentally demonstrated that α″-Fe16N2 foils, as a candidate for rare-earth-free magnets, have an ultralow positive TCC (0.4 Oe/K) from 300 K to 425 K. It is two orders of magnitude smaller than that of the commercial NdFeB magnets in this temperature range. The α″-Fe16N2 foils are made from as-rolled iron foils (25 µm) by a low-temperature nitridation process (< 473 K). The microstructure of these iron foils is tuned before the nitridation by a combined oxidation and reduction process to induce pores and defects that could significantly enhance the diffusivity of nitrogen atoms in the foils. The fabricated α″-Fe16N2 foils exhibit the specific saturation magnetization up to 222 emu/g at 300 K (reduced iron foils ~ 205 emu/g) and the coercivity 1.1 kOe. The synthesized α″-Fe16N2 foils have an ultralow TCC and a high saturation magnetization besides its usages of low-cost and environment-friendly raw materials. These combined unique features make α″-Fe16N2 a promising rare-earth-free alternative for many applications required less temperature dependence of magnetic properties.
Original language | English (US) |
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Pages (from-to) | 143-150 |
Number of pages | 8 |
Journal | Acta Materialia |
Volume | 184 |
DOIs | |
State | Published - Feb 1 2020 |
Bibliographical note
Publisher Copyright:© 2019 Acta Materialia Inc.
Keywords
- Low-temperature nitridation
- Permanent magnet
- Porous structure
- Rare-earth-free magnets
- α″-FeN foils