Synthesis of (chlorovinyl)cobaloxime complexes, model complexes of proposed intermediates in the B12-catalyzed dehalogenation of chlorinated ethylenes

Autumn E. Rich, Angela D. DeGreeff, Kristopher McNeill

Research output: Contribution to journalArticlepeer-review

30 Scopus citations

Abstract

(Chlorovinyl)cobaloxime complexes, (dmgH)2(py)CoR (R = cis-dichlorovinyl, trans-2-chlorovinyl or 1-chlorovinyl, dmgH = dimethylglyoximate) were synthesized from the reaction of chlorinated ethylenes with in situ generated (dmgH)2Co(I) in the presence of pyridine.

Original languageEnglish (US)
Pages (from-to)234-235
Number of pages2
JournalChemical Communications
Issue number3
StatePublished - Feb 7 2002

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