Abstract
We present the temperature- and thickness-dependent structural and morphological evolution of strain-induced transformations in highly strained epitaxial BiFeO 3 films deposited on LaAlO 3 (001) substrates. Using high-resolution x-ray diffraction and temperature-dependent scanning-probe-based studies, we observe a complex temperature- and thickness-dependent evolution of phases in this system. A thickness-dependent transformation from a single, monoclinically distorted, tetragonal-like phase to a complex mixed-phase structure in films with thicknesses up to ∼200 nm is the consequence of a strain-induced spinodal instability in the BiFeO 3/LaAlO 3 system. Additionally, a breakdown of this strain-stabilized metastable mixed-phase structure to nonepitaxial microcrystallites of the parent rhombohedral structure of BiFeO 3 is observed to occur at a critical thickness of ∼300 nm. We further propose a mechanism for this abrupt breakdown that provides insight into the competing nature of the phases in this system.
Original language | English (US) |
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Article number | 024113 |
Journal | Physical Review B - Condensed Matter and Materials Physics |
Volume | 85 |
Issue number | 2 |
DOIs | |
State | Published - Jan 13 2012 |
Externally published | Yes |