TY - JOUR
T1 - The chemistry of the group V metal carbonyls IV. Mixed metal seven-coordinate complexes
AU - Davison, A.
AU - Ellis, J. E.
PY - 1972/3/1
Y1 - 1972/3/1
N2 - The preparation of the main group mixed metal complexes (C6H5)3SnM(CO)6, (C6H5)3SnM(CO)5(C6H5)3P, (C6H5)3SnM(CO)4[(C6H5)2PCH2]2; (C6H5)3PAuM(CO)6, (C6H5)3PAuM(CO)5(C6H5)3P; C2H5HgM(CO)6, C2H5HgM(CO)5(C6H5)3P where M = V, Nb or Ta is described. The unsubstituted complexes are very prone to heterolytic cleavage in weak donor solvents. This behavior, as well as that for the phosphine substituted complexes, is discussed in relationship to the synthesis of mixed metal complexes.
AB - The preparation of the main group mixed metal complexes (C6H5)3SnM(CO)6, (C6H5)3SnM(CO)5(C6H5)3P, (C6H5)3SnM(CO)4[(C6H5)2PCH2]2; (C6H5)3PAuM(CO)6, (C6H5)3PAuM(CO)5(C6H5)3P; C2H5HgM(CO)6, C2H5HgM(CO)5(C6H5)3P where M = V, Nb or Ta is described. The unsubstituted complexes are very prone to heterolytic cleavage in weak donor solvents. This behavior, as well as that for the phosphine substituted complexes, is discussed in relationship to the synthesis of mixed metal complexes.
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U2 - 10.1016/S0022-328X(00)85128-1
DO - 10.1016/S0022-328X(00)85128-1
M3 - Article
AN - SCOPUS:0000673683
SN - 0022-328X
VL - 36
SP - 113
EP - 130
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 1
ER -