The chemistry of the group V metal carbonyls V. The preparation of derivatives of tetracarbonyl-[1,2-bis(diphenylphosphino)ethane]vanadium(0)

A. Davison, John E Ellis

Research output: Contribution to journalArticlepeer-review

39 Scopus citations

Abstract

Convenient synthesis of HV(CO)4[(C6H5)2PCH2]2, IV(CO)4[(C6H5)2PCH2]2, and V(CO)4[(C6H5)2PCH2]2 from [(C2H5)4N] {V(CO)4[(C6H5)2PCH2]2} are described. The chemistry of the new hydrido and iodo derivatives is discussed in relationship to the parent carbonyl and other derivatives of vanadium hexacarbonyl.

Original languageEnglish (US)
Pages (from-to)131-136
Number of pages6
JournalJournal of Organometallic Chemistry
Volume36
Issue number1
DOIs
StatePublished - Mar 1 1972

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