The Claisen Rearrangement of Iron Allyloxy Carbene Complexes

Anthony G.M. Barrett, Nancy E Carpenter

Research output: Contribution to journalArticlepeer-review

33 Scopus citations

Abstract

Several cationic iron(II) allyloxy carbene complexes have been prepared from the corresponding iron vinylidenes {Fe(ή5-C5H5)(CO)[P(OCH3)3](C= CR1R2}+X” (X =BF4, OSO2CF3). These compounds have been deprotonated with KH and 18-crown-6 and thermally rearranged in situ to give the corresponding γ,δ-unsatu-rated iron acyl complexes in moderate yields.

Original languageEnglish (US)
Pages (from-to)2249-2250
Number of pages2
JournalOrganometallics
Volume6
Issue number10
DOIs
StatePublished - Oct 1 1987
Externally publishedYes

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